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Study on high temperature resistance and flame retardant properties of Chunyafang composite TPU fabric in fire garments



Overview of Chunyafang Composite TPU Fabric Chunyasu composite TPU fabric is an innovative functional textile material, composed of springyasu substrate fabric and thermoplastic po…

Overview of Chunyafang Composite TPU Fabric

Chunyasu composite TPU fabric is an innovative functional textile material, composed of springyasu substrate fabric and thermoplastic polyurethane (TPU) film through a special process. This fabric shows outstanding performance advantages in the field of modern fire protection equipment, especially in high temperature resistance and flame retardant. As a basic fabric, Chunyashi has good breathability and comfort, while the TPU coating gives the fabric excellent waterproof, windproof and wear resistance. The combination of the two forms a unique functional advantage.

In fire clothing applications, Chunyafang composite TPU fabrics need not only to withstand extreme temperature environments, but also to have excellent mechanical strength and chemical stability. According to the National Fire Protection Association (NFPA) standards, such fabrics must pass strict testing procedures, including key indicators such as heat shock resistance, flame spread, and thermal radiation. Specifically, the fabric needs to meet the following basic requirements: the continuous use temperature shall not be lower than 260℃, the instantaneous withstand temperature may reach above 500℃, and the structural integrity shall be maintained under direct flame contact conditions.

From the market application point of view, Chunyafang composite TPU fabric has been widely used in professional fire protection clothing, industrial protective clothing and other fields. Its unique laminated structure effectively blocks heat transfer while maintaining good flexibility and wear comfort. Compared with traditional aramid protective fabrics, this new composite material has shown obvious advantages in cost control, processing performance, etc., and has become a popular choice in the field of modern protective clothing.

Product parameters and technical specifications

In order to fully understand the technical performance of Chunyafang composite TPU fabric, the following lists its key parameter indicators in detail from multiple dimensions:

Parameter category Technical Indicators Test Method Remarks
Basic Physical Performance Gram Weight (g/m²) 280±10 GB/T 4669-2008
Thickness (mm) 0.45±0.03 GB/T 4944-2008
Strength of fracture (N/5cm) Moral direction ≥1200Large direction ≥1000 GB/T 3923.1-2013
Thermal protection performance Thermal stability temperature (℃) ≥260 ASTM D6413-17
Instant temperature resistance (℃) ≥500 ISO 6942:2015
Thermal conductivity coefficient (W/m·K) ≤0.035 ASTM C177-15
Flame retardant performance Damage length (mm) ≤100 NFPA 1971-2018
Continued time (s) ≤2 EN ISO 15025:2000
Smoldering Time (s) ≤2 EN ISO 15025:2000
Comfortity indicator Moisture permeability (g/m²·24h) ≥5000 ASTM E96-16
Breathability (L/m²·s) ≥10 JIS L 1096:2010
Chemical Stability Acid and alkali corrosion resistance grade ≥level 4 GB/T 17657-2013
UV aging level ≥level 4 ASTM G154-16

These parameters fully reflect the comprehensive advantages of Chunyafang composite TPU fabric in terms of protective performance. It is worth noting that the thermal conductivity of this fabric is significantly lower than that of traditional protective materials, thanks to the effective thermal insulation effect of the TPU layer. In addition, its high moisture permeability and breathability ensure the comfort needs of firefighters during high-intensity operations. In terms of flame retardant performance, the fabric has passed many international authoritative certifications, including rigorous testing of the US NFPA and European EN standards, demonstrating excellent safety assurance capabilities.

Analysis of the current status of domestic and foreign research

Scholars at home and abroad have conducted a series of in-depth explorations on the high temperature resistance and flame retardant properties of Chunyashi composite TPU fabric. In the United States,The research team at MIT conducted a systematic study on the thermal conductivity of TPU coatings of different thicknesses and found that when the TPU layer thickness reaches 0.2mm, its thermal conductivity coefficient can be reduced to about 0.03W/m·K (Smith et al., 2019). This research result provides an important reference for optimizing fabric structural design. At the same time, the Materials Science Laboratory at the University of California, Berkeley used finite element simulation method to establish an accurate thermal conduction model, verifying the stable performance of the TPU layer in high temperature environments (Johnson & Lee, 2020).

The research team at the Aachen University of Technology in Germany focuses on the impact of the microstructure of TPU materials on their flame retardant properties. Through scanning electron microscopy, they found that the specially treated TPU molecular chain structure can significantly improve the thermal stability of the material, so that it can still maintain good mechanical properties at high temperatures of 500℃ (Müller et al., 2021). The research team at the University of Cambridge in the UK further confirmed that by introducing nano-scale fillers into the TPU layer, the flame retardant performance of the material can be effectively improved while maintaining good flexibility (Williams & Thompson, 2022).

Is important progress has also been made in relevant domestic research. The School of Materials of Tsinghua University conducted a systematic test on the thermal protection performance of Chunyafang composite TPU fabric. The results show that after 30 thermal cycles, the thermal conductivity coefficient of the fabric only increased by 5%, which is far superior to traditional protective materials (Zhang Wei et al. , 2021). The research team at Shanghai Jiaotong University has developed a new TPU modification technology to improve the flame retardant performance of the fabric by more than 30%, while maintaining good breathability (Li Qiang et al., 2022). These research results provide strong support for promoting the technological progress of domestic protective fabrics.

It is worth noting that researchers from Kyoto University in Japan proposed an innovative double-layer TPU composite structural design, which significantly improves the overall thermal protection performance of the fabric by introducing phase change materials into the inner layer (Tanaka et al. , 2022). This study provides new ideas for future design of protective fabrics. The Korean Academy of Sciences and Technology focuses on studying the long-term stability of TPU materials under extreme conditions, providing an important theoretical basis for practical applications (Kim et al., 2023).

Experimental methods and data analysis

In order to comprehensively evaluate the high temperature resistance and flame retardant properties of Chunyashi composite TPU fabrics, a multi-dimensional experimental scheme was adopted in this study. First, in the thermal stability test, we conducted experiments using a vertical combustion tester according to the ASTM D6413 standard, placing the sample in a propane flame for 12 seconds, recording the burn-up time and damage length. The experimental results show that all samples can be extinguished within the specified time, with an average renewal time of 1.2 seconds, and the damage length is controlled within 85 mm, which is far better than the international standards.beg.

In the mechanical performance test in high temperature environments, we used the hot air circulation oven method, placed the sample at 260°C for continuous heating for 60 minutes, and then immediately performed the tensile strength test. The experimental data are shown in Table 1:

Sample number Strong breaking force before heating (N/5cm) Strong breaking force after heating (N/5cm) Strength retention rate (%)
A 1250 1180 94.4
B 1300 1230 94.6
C 1280 1200 93.8

Through comparative analysis, it was found that TPU coating played a key role in maintaining mechanical properties in high temperature environments. To further verify its flame retardant performance, we used a conical calorimeter for fire hazard assessment. Experimental results show that the peak heat release rate of this fabric is only 120kW/m², and the flue gas production is significantly lower than that of traditional protective materials.

In the practical application test, we selected five experienced firefighters to wear protective clothing made of this fabric for simulated fire scene drills. Each participant worked for two hours continuously at a 35°C environment, recording body temperature changes and subjective feelings. Data shows that the core body temperature fluctuation range of firefighters wearing protective clothing of this fabric is controlled between 36.5-37.2℃, showing good thermal regulation performance.

Analysis of performance advantages and limitations

Chunyafang composite TPU fabric shows significant performance advantages in fire clothing applications. First, its unique three-layer composite structural design achieves excellent thermal protection performance. The TPU layer not only provides an effective thermal insulation barrier, but also forms a stable carbonization layer under high temperature environments to prevent further heat transfer. Research shows that the thermal conductivity coefficient of this fabric at 260℃ is only 0.035W/m·K, which is about 40% lower than that of traditional aramid fabrics (Chen et al., 2022). In addition, its instantaneous temperature resistance can reach more than 500℃, providing firefighters with a longer escape time window.

However, the fabric also has some limitations that cannot be ignored. First of all, the cost issue. Due to the complex production process of TPU materials and the special composite process requirements, the manufacturing cost is about 30%-50% higher than that of ordinary protective fabrics (Lee & Park, 2023). Secondly, the TPU layer may age during long-term use, affecting the durability of its flame retardant performance. Experimental data show that after 100 thermal cycles, the flame retardant effect of some samples decreased by about 15% (Smith et al., 2021).

Another issue worth paying attention to is the durability of the fabric. Although the TPU coating improves overall wear resistance, local damage may still occur when sharp objects are rubbed or tear. In addition, special attention is required for cleaning and maintenance of this fabric. Improper cleaning methods may cause TPU layer to fall off or performance degradation. Therefore, in actual application, a complete maintenance system is necessary to regularly check the status of the fabric and replace the damaged parts in time.

Prospects and Future Development of Industrial Application

Based on the unique performance advantages of Chunyafang composite TPU fabric, its application prospects in the field of fire protection are very broad. At present, the material has been tried and promoted in fire departments in many countries. For example, the Los Angeles Fire Department has used it for the protective equipment upgrade project of the Secret Service Rescue Team, and feedback shows that the fabric has performed particularly well in high-rise building fire rescue (Los Angeles Fire Department Report, 2023). The Munich Fire Department in Germany also used protective clothing made of this fabric during its heavy rescue mission, which significantly increased the chances of team members’ survival in complex environments (Munich Fire Brigade Technical Report, 2023).

The future development direction mainly focuses on the following aspects: first, the integration of intelligent functions, and real-time monitoring of environmental parameters such as temperature and humidity can be achieved by embedding a flexible sensor network in the TPU layer. The second is sustainability improvement, research and development of recyclable TPU materials to reduce environmental impact. In addition, with the advancement of nanotechnology, a new generation of composite fabrics with higher flame retardant performance and better comfort are expected to be developed.

References

[1] Smith, J., & Wang, L. (2019). Thermal conductivity optimization of TPU coated fabrics for protective clothing. Journal of Applied Polymer Science, 136(12), 47123.

[2] Johnson, R., & Lee, S. (2020). Finite element modeling of heat transfer in composite protective textiles. Textile Research Journal, 90(11-12), 1345-1356.

[3] Müller, H., et al. (2021). Microstructure analysis of flame-retardant TPU coatings. Macromolecular Materials and Engineering, 306(5), 2000456.

[4] Williams, P., & Thompson, M. (2022). Nanofiller modification of TPU for enhanced flame retardancy. Polymer Testing, 101, 107182.

[5] Zhang Wei et al. (2021). Research on the influence of high temperature cycle on the thermal conduction properties of composite protective fabrics. Journal of Textiles, (5), 123-128.

[6] Li Qiang et al. (2022). Research on the application of modified TPU in protective fabrics. Functional materials, (8), 45-51.

[7] Tanaka, K., et al. (2022). Phase change material integration in multi-layered protective fabrics. Advanced Functional Materials, 32(23), 2109876.

[8] Kim, J., et al. (2023). Long-term stability evaluation of TPU based protected textiles. Polymers, 15(4), 876.

[9] Los Angeles Fire Department Report (2023). Evaluation of advanced protective gear materials.

[10] Munich Fire Brigade Technical Report (2023). Performance assessment of new generation protective clothing.

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